Science & Tech · Science & Environment · 4 hrs ago

Low-cost nickel catalyst comes within 50 millivolts of ruthenium

Low-cost nickel catalyst comes within 50 millivolts of ruthenium

Researchers developed nickel- and iron-based catalysts for green hydrogen using common materials rather than costly precious metals.

Green hydrogen is made by using electricity to split water into hydrogen and oxygen, and it produces no carbon dioxide when the electricity comes from renewable sources.

The team grew carbon nanofibers on a conductive material called MXene and added particles of nickel oxide or iron oxide.

In tests of oxygen production, the nickel catalyst came within 50 millivolts of ruthenium oxide, a benchmark catalyst.

That result matters because most hydrogen today is made from fossil fuels, while expensive catalysts can raise the cost of making hydrogen by splitting water.

In full water-splitting cells, the iron catalyst performed better initially, reaching the target current at 2.2 volts compared with 2.7 volts for the nickel version.

Both prototype cells stayed stable during a 24-hour test, but the materials have not yet matched platinum for hydrogen production; the researchers say the approach could offer a scalable route to catalysts made from abundant materials.

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Growing the fibers directly on the MXene sheets gave us a conductive backbone and a lot of accessible active sites
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